Study on power generation and Congo red decolorization of 3D conductive PPy-CNT hydrogel in bioelectrochemical system

In this paper, a polypyrrole-carbon nanotube hydrogel (PPy-CNT) with 3D macroporous structure was prepared by secondary growth method. This self-supporting material with good conductivity and biocompatibility can be directly used as anode in a microbial fuel cell (MFC). The prepared material had a uniform structure with rich 3D porosity and showed good water retention performance. The effect of the mass ratio of PPy and CNT in the hydrogel were also investigated to evaluate the electrical performance of MFC. The MFC with 10:1 PPy-CNT hydrogel anode could reached the maximum power density of 3660.25 mW/m3 and the minimal electrochemical reaction impedance of anode was 5.06 Ω. The effects of Congo red concentration, external resistance and suspended activated sludge on decolorazation and electricity generation were also investigated in the MFC with the best performance hydrogel. When the Congo red concentration was 50 mg/L and the external resistance was 200 Ω, the dye decolorization rate and chemical oxygen demand (COD) removal rate could reach 94.35% and 42.31% at 48h while the output voltage of MFC was 480 mV. When activated sludge was present, the decolorization rate and COD removal rate could be increased to 99.55% and 48.08% at 48 h. The above results showed that the porous hydrogel anode had broad application prospects in synchronous wastewater treatment and electricity production of MFC.     

Preparation and characterization of Cf/Pollucite composites through geopolymer precursors

Continuous carbon-fibre-reinforced Cs-geopolymer composite (C_f/CsGP) were prepared, and its in-situ conversion was investigated during high-temperature treatments. The effect of treatment temperature on the thermal evolution process and mechanical properties of the resulting products were systematically evaluated. The results indicated that the crystallization temperature of C_f/CsGP composite was considerably delayed because the amorphous structure of carbon fibres was not conducive as a nucleation substrate for pollucite derived from the CsGP matrix. Moreover, the integrity of the corresponding resulting products derived from the C_f/CsGP composite were damaged due to thermal shrinkage that occurred during the high-temperature treatment process. When treatment temperature was ≤1200^oC, the mechanical properties of the corresponding products exhibited an upward trend, which was ascribed to the improvement of the densification degree of the resulting composite and well interface-bonding state between carbon fibres and pollucite. However, the mechanical properties of the resulting composites decreased with the treatment temperature continued increased from 1200 to 1400^oC. This phenomenon was attributed to the impairment of fibre properties caused by interfacial reactions.     

Fabrication of NixCo3-xS4 hollow nanosphere as wideband electromagnetic absorber at thin matched thickness

Nowadays, transition metal sulfide (TMS), especially for spinel crystal structure (A_xB_3-xS₄), have been proved to be a promising electromagnetic (EM) absorber if been used to deal with the severe electromagnetic pollution. However, EM performance degradation and absorption layer thickness-decreasing at present remains a big challenge, owning to the poor EM attenuation ability. To overcome this barrier, herein we reported a Ni_xCo_3-xS₄ (x = 0, 0.3, 0.6, 1.0) absorber with hollow sphere structure to realize a good EM performance with a thinner matched thickness (<1.5 mm). The average sizes of these Ni_xCo_3-xS₄ distributed in 450–550 nm. The dielectric loss ability (ε'') can be boosted by tuning the molar ratio of Ni/Co, which attributes to EM performance. Additionally, hollow structure would lead to the electromagnetic multi-reflection, also benefited to EM performance. The results demonstrated that the maximum qualified absorption bandwidth (f_E) of 3.8 GHz can be achieved for the Ni_0·3Co_2·7S₄ sample when specimen thickness only equals to 1.3 mm.     

面向草莓抓取的气动四叶片软体抓手研制

农林业中果蔬的自动化采摘需求日趋强烈,末端抓手是实现无损采摘的关键。传统的末端抓手以刚性结构居多,现有的各种柔性抓手也存在抓取力不足、包覆性不佳等缺点。本文以草莓的无损采摘为研究对象,提出将草莓外部轮廓曲线作为设计曲线,设计了一种新型气动四叶片软体抓手。首先,对软体抓手的结构做仿真优化,提出一种安全地附着在目标物表面的设想。然后,在进行草莓表面的最小破坏应力试验的基础上,测试了软体抓手的末端力,验证了其实现无损抓取的可行性。再次,利用动态捕捉技术,研究了软体抓手叶面的弯曲变形规律。最后,选择使用弧线型气体通道的软体抓手进行了草莓抓取测试,结果证明了气动四叶片软体抓手可以实现草莓的无损抓取,抓取成功率达90%,破损率为2%,表明所研制的四叶片软体抓手用于草莓抓取时具有良好的稳定性和实用性,可用于草莓采摘的末端执行器。本研究也可为其他易损果蔬的采摘技术提供理论基础和技术支撑。     

Medical image detection and azithromycin in the treatment of pelvic inflammation based on intelligent hospital system

The pelvic infection and people genital tract inflammation, infertility, chronic pain, and reasons for detecting ectopic pregnancy. Diagnostic and management challenges, from different signs and symptoms and a variety of microbial etiology is not fully delineated largely responsible. Because of the potential for serious things of the network, it is recommended for the diagnosis and treatment of low barriers to entry. One of pelvic inflammatory infection of pregnant woman of childbearing age is not the most testing an important public pelvic problem remains. This is the main long-term internet of things, such as tubal factor infertility, ectopic pregnancy and chronic pelvic pain. Also, acute care and its complications lead to significant pelvic care costs. These long-term preventions of the internet of things depend on the microbial cause of acute knowledge of strategies based on treatment. All aware that it is a polymicrobic acute infection. Organisms, Chlamydia trachomatis and Neisseria gonorrhoeae sexually transmit presence, in many cases, including the endogenous vaginal and cervical flora often associated with microorganisms. It contains anaerobic and facultative bacteria similar to those associated with bacterial most importantly mycoplasma has also recently been involved in acute reasons. Therefore, a therapeutic regimen for acute should provide a wide spectral range that is effective against these microorganisms.     

Efficient hydrogen production for industry and electricity storage via high-temperature electrolysis

The paper describes the development status of Sunfire's reversible solid oxide cell (RSOC) technology. Here, Sunfire is a pioneer in the field of high-temperature electrolysers (HTE) for renewable hydrogen production which can be operated as a fuel cell for power generation in a reverse mode. The maturity of the technology is improved stepwise so that first applications in the field of hydrogen production for industry and electricity storage can be tackled. Three application examples where larger scale prototype has been installed will be discussed: 1) A power-to-power electricity storage based on hydrogen, 2) a RSOC unit that is installed in an iron and steel works, and 3) a pressurized SOEC prototype which will be integrated with a methanation unit. Results show the potentials of the technology in connection with fluctuating renewable energy sources.     

Novel nanorod Ti0·7Ir0·3O2 prepared by facile hydrothermal process: A promising non-carbon support for Pt in PEMFCs

Late transition metal doped TiO₂ has been exploited for generating efficient catalyst support by enhancing electrical conductivity and modifying properties of TiO₂. The Ti_0·7Ir_0·3O₂ nanorod (NRs), a novel catalyst support for Pt nanoparticles, was prepared for the first time via single-step hydrothermal process at low temperature using IrCl₃·3H₂O and TiCl₄ as starting materials. We found that the Ti_0·7Ir_0·3O₂ NRs with 70–80 nm in length and 25–30 nm in width is successful prepared at 210 °C for 12 h without utilizing surfactants or stabilizers. In addition, the Ti_0·7Ir_0·3O₂ NRs was presented principally as a single-phase solid with the TiO₂ is in the rutile form with high crystallinity without using further treatment after synthesis. More importantly, we found that the Ti_0·7Ir_0·3O₂ NRs possesses high electrical conductivity (0.028 S cm⁻¹) dealing the intrinsically non-conducted drawback of TiO₂. The Pt nanoparticles were then deposited on the support of Ti_0·7Ir_0·3O₂ NRs via chemical reduction method. The properties of 20 wt % Pt/Ti_0·7Ir_0·3O₂ NRs electrocatalyst were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), the cyclic voltammetry (CV). The uniformly distributed small Pt nanoparticles (3–4 nm diameter) were well adhered to the Ti_0·7Ir_0·3O₂ NRs. The electrochemically active surface area (ECSA) of 20 wt % Pt/Ti_0·7Ir_0·3O₂ NRs was higher than that of the commercial 20 wt % Pt/C (E-TEK) due to the small size and good dispersion of Pt nanoparticles on the surface of Ti_0·7Ir_0·3O₂ NRs. Moreover, the ECSA value of the Pt/Ti_0·7Ir_0·3O₂ NRs retained up to 88% after 2000 cycles of cyclic voltammetry, suggesting the high stability of catalyst resulted from strong metal support interaction (SMSI) of Titania-based materials with the noble metals. More importantly, the onset potential of Pt/Ti_0·7Ir_0·3O₂ NRs catalyst towards oxygen reduction reaction is more positive (∼80 mV) compared to commercial Pt/C, indicating the high catalytic activity of the Pt/Ti_0·7Ir_0·3O₂ NRs catalyst. The results of this research suggested that novel Ti_0·7Ir_0·3O₂ NRs could be applied as promising robust non-carbon support for Pt. This research also creates a preliminary step for investigating systematically promising Iridium doped Titania materials.     

Numerical investigation of gelled crude oil particle melting in water for hydrogen production

This paper describes a numerical analysis of the melting process of gelled crude oil in water for hydrogen production. The melting characteristics of crude oil particles are analyzed, and the influence of flow velocity, particle radius, and hot water temperature on the melting process is discussed. The results indicate that the melting rate on the surface of the crude oil is different, the oil particles do not melt concentrically, and the monitoring points and rate of increase in temperature are not substantially affected by the phase change interval. The flow rate and particle radius are found to have a significant influence on the phase distribution of the oil droplets, but changes in water temperature have little effect. After validating a model of the melting process, we investigate the influence of oil particle size, water temperature, flow rate, and oil temperature. It is found that increases in water temperature and flow rate, or a decrease in oil particle size, tend to reduce the melting time.     

A novel utilized method of tar derived from biomass gasification for fabricating binder-free all-solid-state hybrid supercapacitors

As an industrial pollutant, tar derived from biomass gasification is used as the precursor for fabricating a novel carbon-metal hydroxides composite electrode. A slurry (the mixture of tar, KOH and melamine) is daubed uniformly onto the nickel foam, which is directly carbonized to form NPC@LDH electrode material. This electrode is further coated with NiCo-LDH nanosheets using an electrodeposition method to form NF@NPC@LDH. The newly made NF@NPC@LDH electrode exhibits a high specific capacity of 9.6 F cm⁻² at a current density of 2 mA cm⁻² and good rate performance (55.3% retention). Furthermore, a hybrid NF@NPC@LDH//NF@PC all-solid-state supercapacitor is fabricated, and the device exhibits high energy density of 1.28 mWh cm⁻³ at a power density of 8.04 mW cm⁻³, low resistance and good cycling stability.